Tailoring covalent organic frameworks for application in catalysis and water monitoring
Laura M. Salonen
CINBIO, Universidade de Vigo, Department of Organic Chemistry, 36310 Vigo, Spain
E-mail: lauramaria.salonen@uvigo.es
Molecular framework materials allow for the precise placement of building blocks in a crystalline matrix, which is highly advantageous in tailoring materials towards a specific purpose. Covalent organic frameworks (COFs) are a member of this class of materials, which, with their crystalline, highly ordered, and porous nature, are receiving increasing interest for various applications.
In this talk, synthetic approaches to obtain crystalline, functionalized COFs will be discussed.[1],[2] Different strategies to furnish the materials with catalytic activity will be presented, as well as our results on the stability of COFs under catalytically relevant conditions.[3],[4],[5] On the other hand, key aspects on the design and synthesis of COFs for contaminant capture from water will be considered.[6],[7]
[1] L. Frey, O. Oliveira, A. Sharma, R. Guntermann, S. P. S. Fernandes, K. M. Cid-Seara, H. Abbay, H. Thornes, J. Rocha, M. Döblinger, T. Kowalczyk, A. Rao, L. M. Salonen, D. D. Medina, Angew. Chem. Int. Ed. 2023, e202302872.
[2] S. P. S. Fernandes, L. Frey, K. M. Cid-Seara, O. Oliveira, C. Rodríguez-Abreu, Yu. V. Kolen’ko, N. Guldris, E. Carbó-Argibay, A. M. S. Silva, D. D. Medina, L. M. Salonen, Microporous Mesoporous Mater. 2022, 343, 112162.
[3] S. T. Goralski, K. M. Cid-Seara, J. J. Jarju, L. Rodriguez-Lorenzo, A. P. LaGrow, M. J. Rose, L. M. Salonen, Chem. Commun. 2022, 58, 12074.
[4] J. J. Jarju, A. M. Díez, L. Frey, V. Sousa, L. P. L. Gonçalves, D. D. Medina, O. I. Lebedev, Yu. V. Kolen´ko, L. M. Salonen, Mater. Today Chem. 2022, 26, 101032.
[5] L. P. L. Gonçalves, J. Garcia Ben, K. Strutyński, L. Rodriguez-Lorenzo, J. Araújo, A. S. G. G. Santos, O. S. G. P. Soares, M. F. R. Pereira, Yu. V. Kolen’ko, M. Melle-Franco, L. M. Salonen,Microporous and Mesoporous Mater. 2024, 366, 112916.
[6] S. P. S. Fernandes, V. Romero, B. Espiña, L. M. Salonen, Chem. Eur. J. 2019, 25, 6461–6473.
[7] S. P. S. Fernandes, P. Kovář, M. Pšenička, A. M. S. Silva, L. M. Salonen, B. Espiña, ACS Appl. Mater. Interfaces 2021, 13, 15053–15063.
